Xu, Y., Chen, X., Gu, B.L., Duan, W.: Intrinsic anisotropy of thermal conductance in graphene nanoribbons. J. Note the primitive cell may appear less symmetric than the conventional cell representation (see "Structure Type" selector below the 3d structure). Phys. Phys. Phys. It should be noted that ComputedEntries assimilated using the : Resolving the in-plane anisotropic properties of black phosphorus. However, as the first element of group V, nitrogen has never been found in the black phosphorus structure. J. Phys. Over 10 million scientific documents at your fingertips. View JMOL 3-D Structure : Phosphorus : Cartz L, Srinivasa S R, Riedner R J, Jorgensen J D, Worlton T G : Journal of Chemical Physics 71 (1979) 1718-1721: Effect of pressure on bonding in black phosphorus: Locality: synthetic: Note: pressures calculated from the measured unit cell volume _database_code_amcsd 0013008: … ACS Nano, Guo, H., Lu, N., Dai, J., Wu, X., Zeng, X.C. Ed. Xu, J.Y., Gao, L.F.C., Hu, X., Zhu, Z.Y., Zhao, M., Wang, Q., Zhang, H.L. Qiao, J., Kong, X., Hu, Z.X., Yang, F., Ji, W.: High-mobility transport anisotropy and linear dichroism in few-layer black phosphorus. Lan, S., Rodrigues, S., Kang, L., Cai, W.: Visualizing optical phase anisotropy in black phosphorus. Especially, there emerge contributions on electrochemical energy storage devices as supercapacitors and in batteries like lithium/sodium ion batteries. Commun. Jain, A., McGaughey, A.J.H. The role of inorganic chemistry is presented, the black phosphorus surface being a potential anchoring point for metal fragments. Angew. Fig. Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914. The catalytic representation of black phosphorus. : Isolation and characterization of few-layer black phosphorus. Phys. Phosphorus pentoxide was used in the early and mid-20thcentury to procure phosphoric acid, by dissolving the former in water. : Lattice vibrational modes and phonon thermal conductivity of monolayer MoS. Rev. Int. Engl. 2D Mater. Ed. Viti, L., Hu, J., Coquillat, D., Knap, W., Tredicucci, A., Politano, A., Vitiello, M.S. 'PAW_PBE O 08Apr2002']. B. Qin, G., Yan, Q.B., Qin, Z., Yue, S.Y., Cui, H.J., Zheng, Q.R., Su, G.: Hinge-like structure induced unusual properties of black phosphorus and new strategies to improve the thermoelectric performance. ACS Nano, Lv, H.Y., Lu, W.J., Shao, D.F., Sun, Y.P. Rev. Here, we report the synthesis of the black phosphorus–structured nitrogen at 146 GPa and 2200 K. Metastable black … J. Withers, F., Zamudio, O.D.P., Mishchenko, A., Rooney, A.P., Gholinia, A., Watanabe, K., Taniguchi, T., Haigh, S.J., Geim, A.K., Tartakovskii, A.I., Novoselov, K.S. Mater. Mater. Allg. When red phosphorus is heated in a sealed tube at 803K, an α-black form is formed. Calculated total magnetic moment for the unit cell within the magnetic ordering provided (see below). 2D Mater. There are two shorter (2.22 Å) and one longer (2.26 Å) P–P bond lengths. Adv. Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914. PERSPECTIVE The renaissance of black phosphorus Xi Linga, Han Wangb,1, Shengxi Huanga, Fengnian Xiac, and Mildred S. Dresselhausa,d,1 aDepartment of Electrical Engineering and Computer Science anddDepartment of Physics, Massachusetts Institute of Technology, Cambridge, MA 02139; bMing Hsieh Department of … A sample which had … The energy of decomposition of this material into the set of most stable materials at this chemical composition, in eV/atom. Rev. Mater. Sci. Entry.parameters must contain a "potcar_symbols" key that is a list of Jiang, J.W., Park, H.S. Mater. : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. This chapter summarizes the structure and fundamental properties and few preparation methods of BP. Choi, W., Lahiri, I., Seelaboyina, R., Kang, Y.S. Nat. Select an element to display a spectrum averaged over all It was first synthesized by heating white phosphorus under high pressures (12,000 atmospheres) in 1914. Rev. Miao, J., Song, B., Xu, Z., Cai, L., Zhang, S., Dong, L., Wang, C.: Single pixel black phosphorus photodetector for near-infrared imaging. J. Adv. B. Pumera, M.: Phosphorene and black phosphorus for sensing and biosensing. Phys. Jpn. Ong, Z.Y., Cai, Y., Zhang, G., Zhang, Y.W. Photon. : High-performance n-type black phosphorus transistors with type control via thickness and contact-metal engineering. Mater. Black phosphorus and its exfoliated product, phosphorene, are rising stars in the 2D materials field. Jang, H., Wood, J.D., Ryder, C.R., Hersam, M.C., Cahill, D.G. : J. Phys. Solid State Mater. It can be sublimed in the air and has either rhombohedral crystals or opaque monoclinic. Download spectra for every symmetrically equivalent if you ran a Fe2O3 calculation with Materials Project parameters, Opt. Nano Lett. Nanoscale. Late, D.J. Not logged in : Thermoelectric terahertz photodetectors based on selenium-doped black phosphorus flakes. Through high resolution photon energy dependence measurements, the band dispersions along out-of-plane and in-plane directions are experimentally … Chem. Read article Similar articles. Chem. Eswaraiah, V., Zeng, Q.S., Long, Y., Liu, Z.: Black phosphorus nanosheets: synthesis, characterization and applications. Gomez, A.C., Vicarelli, L., Prada, E., Island, J.O., Narasimha-Archarya, K.L., Blanter, S.I., Groenendijk, D.J., Buscema, M., Steele, G.A., Alvarez, J.V., Zandbergen, H.W., Palacios, J.J., van der Zant, H.S.J. Phys. : Tunable optical properties of multilayer black phosphorus thin films. Mater. History. Rev. Correct anion energies to obtain the right formation energies. Wei, Q., Peng, X.: Superior mechanical flexibility of phosphorene and few-layer black phosphorus Appl. This is the first page of the article you requested. Rev. Mater. : Tuning of the electronic and optical properties of single-layer black phosphorus by strain. Adv. Zhang, R., Zhou, X.Y., Zhang, D., Lou, W.K., Zhai, F., Chang, K.: Electronic and magneto-optical properties of monolayer phosphorene quantum dots. Wang, Z., Jia, H., Zheng, X., Yang, R., Wang, Z., Ye, G., Chen, X., Shan, J., Feng, P.X.L. Cupo, A., Meunier, V.: Quantum confinement in black phosphorus-based nanostructures. It has a layered structure and is a highly polymerizedform of phosphorus. Entry.parameters must contain a "hubbards" key which is a dict Zhao, W., Xue, Z., Wang, J., Jiang, J., Zhao, X., Mu, T.: Large-Scale, Highly efficient, and green liquid-exfoliation of black phosphorus in ionic liquids. : Electrical and thermoelectric transport by variable range hopping in thin black phosphorus devices. : Black phosphorus field-effect transistors. Physica (Amsterdam), Peng, X., Wei, Q., Copple, A.: Strain-engineered direct-indirect band gap transition and its mechanism in two-dimensional phosphorene. Phys. J. Chem. Yang, Y., Gao, J., Zhang, Z., Xiao, S., Xie, H.H., Sun, Z.B., Wang, J.H., Zhou, C.H., Wang, Y.W., Guo, X.Y. In 2014, several groups isolated single-layer phosphorene, a monolayer of black phosphorus. black phosphorus; nanoelectronic; optoelectronic; anisotropic; 2D material; At the beginning of 2014, a few research teams including the ones led by the authors reintroduced black phosphorus (black P) from the perspective of a layered thin film material (1 ⇓ ⇓ ⇓ ⇓ –6), in which previously unidentified properties and applications have arisen.Since then, black … Since the advent of two-dimensional (2D) black phosphorus (which is known as phosphorene due to its resembling graphene sheets) in early 2014, research interest in the arena of black phosphorus was … Soc. Maruyama, Y., Suzuki, S., Kobayashi, K., Tanuma, S.: Synthesis and some properties of black phosphorus single crystals. Am. As a new method of forming phosphoric acid was discovered, this method fell out of fashion. Krebs, H., Weitz, H., Worms, K.H., Anorg. J. using Materials Project parameters, this would look like Follow IUCr Journals: E-alerts: Twitter: Facebook: RSS: Search IUCr Journals: doi: Advanced search: Author TrAC, Trends Anal. : Anisotropic thermal conductivity of exfoliated black phosphorus. : Novel and enhanced optoelectronic performances of multilayer MoS, Cheng, R., Li, D., Zhou, H., Wang, C., Yin, A., Jiang, S., Liu, Y., Chen, Y., Huang, Y., Duan, X.: Electroluminescence and photocurrent generation from atomically sharp WSe. Adv. Crichton, W.A., Mezouar, M., Monaco, G., Falconi, S.: Phosphorus: new in situ powder data from large-volume apparatus. B. Tran, V., Soklaski, R., Liang, Y., Yang, L.: Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Nat. The structure is two-dimensional and consists of two P sheets oriented in the (0, 1, 0) direction. Matter Mater. Am. Black phosphorus is the thermodynamically stable form of phosphorus at room temperature and pressure, with a heat of formationof -39.3 kJ/mol (relative to white phosphorus which is defined as the standard state). It does not oxidize in the air. Rev. : Black phosphorus nanoelectromechanical resonators vibrating at very high frequencies. Black Phosphorus: The Birth of a New Wonder Material. Chen, Y., Jiang, G., Chen, S., Guo, Z., Yu, X., Zhao, C., Zhang, H., Bao, Q., Wen, S., Tang, D., Fan, D.: Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and mode-locking laser operation. 7: Preparation and Properties of Alpha Black Phosphoru… The electronic structure of few-layer (FL) black phosphorus (BP) sensitively depends on the sample thickness, strain, and doping. 1). Small. : Liquid exfoliation of black phosphorus nanosheets and its application as humidity sensor. Li, D., Castillo, A.E.D.R., Jussila, H., Ye, G., Ren, Z., Bai, J., Chen, H.L., Sun, Z., Bonaccorso, F.: Black phosphorus polycarbonate polymer composite for pulsed fibre lasers. Some internal testing by the Materials Project supports these statements; typically, we find that band gaps are underestimated by ~40%. John Timmer - Oct 11, 2020 1:30 pm UTC Enlarge / Layers of phosphorene sheets form black … : J. In 1914 black phosphorus, a layered semiconducting allotrope of phosphorus, was synthesized. Control Release. Materials scientists have discovered how to make black phosphorus nanosheets in large amounts, heralding a new era of nanoelectronic devices. : Two new modifications of phosphorus. B: Condens. Nano Lett. Dhanabalan, S.C., Ponraj, J.S., Guo, Z., Li, S., Bao, Q., Zhang, H.: Emerging trends in phosphorene fabrication towards next generation devices. Soc. The applications of phosphorene and its functionalized derivatives in devices are also reported. J. Phys. J. Phys. Ball-and-stick model of a sheet of phosphorus atoms in black phosphorus. C, Cai, Y., Lan, J., Zhang, G., Zhang, Y.W. We additionally find that several known insulators are predicted to be metallic. Fu, Y., Wei, Q., Zhang, G., Sun, S.: Advanced phosphorus-based materials for lithium/sodium-ion batteries: recent developments and future perspectives. Angew. interface using the pymatgen.matproj.rest package will automatically have Phys. Phys. the Total : The atomic distribution in red and black phosphorus and the crystal structure of black phosphorus. Liu, X., Ryder, C.R., Wells, S.A., Hersam, M.C. : Black phosphorus-based photocathodes in wideband bifacial dye-sensitized solar cells. Engl. B. Chen, Y., Ren, R., Pu, H., Chang, J., Mao, S., Chen, J.: Field-effect transistor biosensors with two-dimensional black phosphorus nanosheets. Int. Lett. Chem. Phys. Nat. Acta Crystallogr. Black Phosphorus can be prepared from white phosphorus as follows: 1. Eng. Angle-resolved photoemission spectroscopy data show that the in situ deposition of potassium atoms on the surface of single-crystalline black phosphorus modulates the band gap in the wide range of 0.0–0.6 eV. Chem. Wang, H., Yang, X., Shao, W., Chen, S., Xie, J., Zhang, X., Wang, J., Xie, Y.: Ultrathin black phosphorus nanosheets for efficient singlet oxygen generation. Microporous Mesoporous Mater. We show that it is also vulnerable to air exposure. Part of Springer Nature. Correct gas energies to obtain the right formation energies. Commun. Black Phosphorus properties: α-black and β-black are two forms of black phosphorus. Chem. Commun. J. USA, Liu, H., Neal, A.T., Zhu, Z., Luo, Z., Xu, X., Tomanek, D., Ye, P.D. Typically the disagreement is reported to be ~50% in the literature. Peng, J., Lai, Y.Q., Chen, Y.Y., Xu, J., Sun, L.P., Weng, J.: Sensitive detection of carcinoembryonic antigen using stability-limited few-layer black phosphorus as an electron donor and a reservoir. Chem. Small, Huang, Y., Liu, X., Liu, Y., Shao, Y., Zhang, S., Fang, C., Han, G., Zhang, J., Hao, Y.: Nanostructured multiple-layer black phosphorus photodetector based on localized surface plasmon resonance. Nat. Sci. Black phosphorus is a semiconductor with a band gap of ~0.3 eV. : A black phosphorus carbide infrared phototransistor. Black Phosphorus. Soc. Rep. Jiang, J.W., Park, H.S. Martinez, C.C.M., Sofer, Z., Pumera, M.: Layered black phosphorus as a selective vapor sensor. Black Phosphorus (Polymeric) Black phosphorus is the most stable form; the atoms are linked together in puckered sheets, like graphite. : Black phosphorus terahertz photodetectors. Mater. Refinement of the crystal structure of black phosphorus. Appalakondaiah, S., Vaitheeswaran, G., Lebegue, S., Christensen, N.E., Svane, A.: Effect of van der Waals interactions on the structural and elastic properties of black phosphorus. structures displayed (dissimilarity threshold 0.75). one of the most common allotropes of phosphorus and is considered to be a derivative of the P4 molecule It is this structure which gives the material its fascinating properties. Up to 5 similar elemental, binary, ternary, quaternary, etc. Mater. Gui, R., Jin, H., Wang, Z., Li, J.: Black phosphorus quantum dots: synthesis, properties, functionalized modification and applications. But this required a supply of white phosphorus, which is comparatively hard to find. Affiliations: 1Material Physics and Technology at Extreme … Express. Black phosphorene has attracted much attention as a semiconducting two-dimensional material. Gomez, A.C.: Black phosphorus: narrow gap, wide applications. : Synthesis of graphene and its applications: A review. entry.parameters["potcar_symbols"] = ['PAW_PBE Fe_pv 06Sep2000', B: Condens. Sun, Z., Xie, H., Tang, S., Yu, X.F., Guo, Z., Shao, J., Zhang, H., Huang, H., Wang, H., Chu, P.K. , Vitiello, M.S K., Vitiello, M.S, properties, structure..., X.C from the elements normalized to per atom in the structure quaternary. About the structure is two-dimensional and consists of two P sheets oriented in the structure, C.W., Davey K.! Be ~50 % in the structure and properties of multilayer black phosphorus a list of all the three allotropes black! Has either rhombohedral crystals or opaque monoclinic J.H., Jang, H., Peeters,.! Discovered how to make black phosphorus Visualizing optical phase anisotropy in black phosphorus-based nanostructures as anisotropic! A highly polymerizedform of phosphorus, a layered structure and is a list of non-zero... 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Fascinating properties Zhu, L.: Eprint Arxiv Arxiv preprintar Xiao, S.: Refinement of the forms of.! In single-layer black phosphorus: tight binding approach, R., Gingrich, N.S., Warren, B.E cm–2 which! Energies to obtain the right formation energies Ishigami, M.: electronic structure of black phosphorus being... Into the set of most stable materials at this chemical composition, in eV/atom nanoribbons, phosphorus nanotubes, structure... Strain-Induced band convergence Lee, Y.H unit cell within the same input set in tight binding approach detail, see...
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